3Dresyn 2PP 10K-XL3 Bio, Biocompatible 10K crosslinker for maximum increase of rigidity & deflection temperature of two photon polymerization 3D resins

3Dresyn 2PP 10K-XL3 Bio is an ultra rigid 10K crosslinker for increasing the rigidity, heat deflection temperature and the aspect ratio without deformation of 2PP 3D resins.

Its use increases the writing speed of slow 2PP resins, as well as their rigidity, hardness, physical and mechanical properties, such as deflection temperature and compression resistance. It also decreases the laser power threshold and permits the printing of high detail and high aspect ratio nano and submicron structures with laser powers of <10 mW.

3Dresyn 2PP 10K-XL3 Bio is normally used up to 5-10% dosage, or more depending on rigidity specifications for certain nano thickness, and it is used for custom adjusting the rigidity of 2PP 3Dresyns.

Designed for use in two photon polymerization workflows as a crosslinker for rigidity, heat deflection temperature and aspect ratio enhancement, and also as a 2PP photocurable resin negative photoresist for high precision additive manufacturing of ultra rigid high aspect ratio 3D nano and microstructures

• Increasing the rigidity of 2PP 3D resins
• Increasing the heat deflection temperature of 2PP 3D resins
• Increasing the aspect ratio without deformation of 2PP 3D resins
• Ultra high aspect ratio vertically printed structures
• High precision additive manufacturing of ultra rigid high aspect ratio 3D nano and microstructures
• Dip-in two-photon lithography DTPL / Dip-in Laser Lithography DiLL
• Conventional Two Photon Lithography TPL systems

• Tensile strength: <70 MPa (ISO 527-1 / ISO 527-2)
• Flexural strength: < 140 MPa (ISO 178)
• Young’s modulus: <10.000 MPa (ISO 527)
• Elongation at break: < 1 % (ISO 527)
• Impact resistance, Notched Izod: <15 J/m (ISO 180:2023)
• Shore hardness: D90 ± 2 (ISO 868)

• Density: 1.0-1.2 g/cm³ (ISO 1675)
• Water absorption: < 0.01 % (24 h at 23°C) (ISO 62)
• Printing shrinkage: no measurable dimensional shrinkage after calibration under validated processing conditions
• Optical transparency: 100% from 440 nm onwards into the Near Infrared NIR
• Viscosity: < 3000 mPas at 23°C ± 2°C (ISO 3219)
• Achievable feature sizes: 100-200 nm

• Heat deflection temperature (HDT): <290 °C @ 0.45 MPa (ISO 75)

• Ultra effective crosslinker: minimum dosage is required for increasing rigidity and deflection temperature
• Ideal for ultra high aspect ratio vertically printed structures
• Based on dioxosilane chemistry with free hydroxyl functionality for further functionalization
• Ideal used alone as 2PP photocurable resin negative photoresist for high precision additive manufacturing of ultra rigid high aspect ratio 3D nano & microstructures with ultra high rigidity and deflection temperature
• Excellent balance of resolution shape accuracy and writing speed
• Photoreactive from 200 to 410 nm with Fine Tuner 2PP FT8 Bio (single 1 photon absorption)
• Photoreactive from 600 to 810 nm with Fine Tuner 2PP FT8 Bio (two photon absorption)
• Decreases the laser power threshold
• Permits the printing of high detail and high aspect ratio nano and submicron structures with laser powers of <10 mW
• Clear, non yellowing
• Durable

• Normally used up to 5-10% dosage, or more depending on rigidity specifications for certain nano thickness
• Designed for Dip-in two-photon lithography DTPL, also referred as Dip-in Laser Lithography DiLL, where the 2PP resin is immersed upside down in the microscope objective
• Designed for conventional 2PP systems, also refered as Two Photon Lithography TPL, where the 2PP resin is positioned upright on the substrate
• Easy handling by direct drop casting
• Good adhesion on glass and other substrates
• Printable by most commercial two photon polymerization printers with wavelengths from 600 nm to 800 nm
• Supplied at different writing speeds: fast, intermediate, slow, and non reactive for custom control of writing speed and resolution
• Tunable with the free sampled Fine Tuner 2PP FT8 Bio for custom adjustment of writing speed
• Tunable with the free sampled Fine Tuner 2PP LB3 Bio for maximum resolution with submicron feature sizes
• Supplied in a relatively low and high viscosity version
• Choose a LV low viscosity version for easy development or cleaning of uncured resin with conventional 2PP upright configurations
• Choose a HV high viscosity version for upside down DiLL configurations
• Easy removal of uncured resin with conventional developers such as isopropanol IPA and propylene glycol methyl ether acetate (PGMEA)
• Ideally use our Cleaning Fluid UNW1 Bio to preserve transparency, prevent whitening and chemical attack of IPA and conventional alcohols
• Please do not expose any 3D resins to natural or room light to prevent their curing.

• Biocompatible
• Synthetic
• Hydrophobic backbone with hydrophilic hydroxyl functionality
• Organo-tin free

Final writing speed, resolution, feature size, rigidity enhancement, heat deflection temperature, aspect ratio, laser power threshold, adhesion, printability and cleaning performance depend on the selected formulation, printer configuration, wavelength, substrate, developer and full processing workflow. Performance must be validated by the user for each specific application.

This material is supplied as a professional manufacturing material and is not marketed as a finished medical device. Final part performance and suitability must be validated by the user according to the intended application.

This technical datasheet should be used together with the relevant processing, calibration, safety and workflow documentation available in the 3Dresyns® Resources section.

Access the 3Dresyns® Technical Resources (IFU, calibration, CRT, post-processing and troubleshooting)